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Oxide Thickness Measurements

Several methods are used for the measurement of thermal oxide thickness.  These include color, mechanical, interference, and ellipsometry.

Color - the easiest method for estimating oxide thickness is to observe the film under illumination by a white light.  Uniform color is evidence of a uniform oxide thickness.  The sensation of a single color is due to the absence of particular frequencies in white light.  The missing frequencies are due to destructive interference as the light is reflected from the oxide-air interface.

Destructive interference occurs when

2d = (2k - 1)l /2n

where d is oxide thickness, k = 1,2,3 order, n = index of refraction of SiO2 film

Color Chart
 

k=1 2 3
Grey 100 A - -
Tan 300 - -
Brown 500 - -
Blue 800 - -
Violet 1000 2800 4600
Blue 1500 3000 4900
Green 1800 3300 5200
Yellow 2100 3700 5600
Sectioning Technique 

In the sectioning technique a wheel is used to grind a slot in the SiO2/Si sample.  By using simple geometry, we can determine the actual thickness of the SiO2 layer

by knowing R, we can determine the thickness of the oxide.

Masking Using SiO2
 
Because of large differences between impurities diffusion coefficiencies.  SiO2 can be used as an effective mask against diffusion.